OPCW issues report on second Technical Assistance Visit to Ukraine following three incidents of alleged use of toxic chemicals as a weapon

OPCW report confirms presence of toxic chemical 2-Chlorobenzylidenemalononitrile, known as CS, related to three alleged incidents that took place along confrontation lines in Dnipropetrovsk region in October 2024

14 February 2025

THE HAGUE, Netherlands— 14 February 2025—Today, the Organisation for the Prohibition of Chemical Weapons (OPCW) has transmitted to Ukraine a report on a second Technical Assistance Visit (TAV) following three separate alleged incidents of use of toxic chemicals as a weapon.  

Upon Ukraine’s request, under subparagraph 38(e) of Article VIII of the Chemical Weapons Convention (CWC), the OPCW Technical Secretariat deployed to Ukraine in relation to three incidents of alleged chemical weapons use along the confrontation lines between opposing forces in the Dnipropetrovsk region. The incidents reportedly took place as follows:

  • On 2 October 2024 near the village of Mariivka;
  • On 12 October 2024 near the village of Illinka;
  • On 14 October 2024 near the village of Illinka.

During their two missions, the experts from the Technical Secretariat (TAV team) collected documentation and digital files, testimonies from first-hand witnesses, and received nine environmental samples collected by Ukraine: four grenade shells, three soil samples, and two vegetation samples collected from locations adjacent to dugouts at an observation post and a resting position, along the confrontation lines with the opposing troops.

Upon return to the OPCW’s Headquarters, the samples were sent to two OPCW designated laboratories selected by the OPCW Director-General, Ambassador Fernando Arias, for independent analysis. This activity was carried out following OPCW procedures and in the presence of observers from the Permanent Representation of Ukraine to the OPCW.

Taken together, the documentation and evidence handed over by Ukraine to the TAV experts during the visits, the content of the digital files provided, as well as the information collected and the narrative described by first-hand witnesses, enabled the TAV experts to corroborate that, as reported by Ukraine to the OPCW TAV team, the chain of custody of the nine samples collected from locations adjacent to dugouts located along the confrontation lines with the opposing troops, had been maintained.

The analyses by the OPCW designated laboratories, conducted separately and independently from one another, confirm that  all the grenades collected from dugouts at the observation post and at the resting position contained the riot control agent CS, CS-related compounds and/or their degradation products; and the soil and vegetation samples collected from the locations where the grenades were initially found lying on the ground also contained CS and/or its degradation products.

This is the second report released by the Technical Secretariat confirming the presence of CS, a riot control agent, in the Dnipropetrovsk region, along the confronting line. The first report was released in November 2024.

Under the CWC, the use of riot control agents as a method of warfare is prohibited.   

Upon receipt of the TAV report this day, the Permanent Representation of Ukraine to the OPCW immediately requested the same day that the Technical Secretariat declassify and share the full report with all States Parties to the CWC and publish it on the OPCW public website.

Director-General Arias, expressed grave concern over the findings, stating: “This report marks the second confirmed instance of riot-control agent grenades being found on the confrontation lines in the Dnipropetrovsk region, further underscoring the urgency of maintaining and enforcing the principles of the Chemical Weapons Convention. More than ever, it is essential to uphold the global norm against chemical weapons and maintain this fundamental prohibition.”

Director-General Arias reaffirmed the Technical Secretariat’s readiness to continue providing its assistance to CWC States Parties through its independent expertise. He also thanked the OPCW designated laboratories that supported the technical assistance request for their independent work and swift analysis.

Background

The OPCW Technical Secretariat has been monitoring the situation on the territory of Ukraine since the start of the war in February 2022 in relation to allegations of use of toxic chemicals as weapons. 

In November 2024, the Technical Secretariat released a report on an OPCW TAV to Ukraine, which confirmed the presence of CS in the samples collected during the TAV. The TAV was conducted in relation to an incident that reportedly took place along the confrontation lines in Dnipropetrovsk region on 20 September 2024.

Both the Russian Federation and Ukraine have accused one another and reported a number of allegations of use of chemical weapons to the Organisation.

A compendium of all official correspondence by States Parties on such allegations and accusations has been made available on the OPCW public website and is regularly updated.

Article II, paragraph 7 of the Chemical Weapons Convention, provides that a Riot Control Agent is defined as any chemical not listed in a Schedule, which can produce rapidly, in humans, sensory irritation or disabling effects which disappear within a short time following termination of exposure.

Under the Convention, States Parties have the obligation to declare all toxic chemical agents they hold for riot control purposes. Furthermore, the Convention explicitly prohibits the use of riot control agents as a weapon of war on the battlefield. If used as a method of warfare, these agents are considered chemical weapons and, hence, are prohibited under Article I paragraph 5 of the Convention.   

Article VIII, paragraph 38(e) of the Chemical Weapons Convention states that the Technical Secretariat shall provide technical assistance and technical evaluation to States Parties in the implementation of the provisions of the Convention, including the evaluation of scheduled and unscheduled chemicals.

OPCW experts and designated laboratories are a lynchpin of the Organisation’s verification regime and its capacity to investigate allegations of chemical weapons use. Upon request from the Director-General, OPCW designated laboratories perform off-site analysis of chemical samples collected during OPCW deployments. They offer the necessary assurance to States Parties that chemical analyses needed to determine or to clarify issues related to such allegations are carried out competently, impartially, and with unambigious results.

As the implementing body for the Chemical Weapons Convention, the OPCW, with its 193 Member States, oversees the global endeavour to permanently eliminate chemical weapons. Since the Convention’s entry into force in 1997, it is the most successful disarmament treaty eliminating an entire class of weapons of mass destruction.

In 2023, the OPCW verified that all chemical weapons stockpiles declared by the 193 States Parties to the Chemical Weapons Convention since 1997 — totalling 72,304 metric tonnes of chemical agents — have been irreversibly destroyed under the OPCW’s strict verification regime.

For its extensive efforts in eliminating chemical weapons, the OPCW received the 2013 Nobel Peace Prize.